Magnetic properties of dinuclear cobalt complexes

被引:37
作者
Ostrovsky, SM
Werner, R
Brown, DA
Haase, W
机构
[1] Tech Univ Darmstadt, Fac Chem, Inst Chem Phys, D-64287 Darmstadt, Germany
[2] Univ Coll Dublin, Dept Chem, Dublin 4, Ireland
关键词
D O I
10.1016/S0009-2614(02)00038-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the magnetic investigation of dinuclear Co(II) compounds on the base of hamiltonian which takes into account exchange interaction, zero-field splitting and Zeeman perturbation. The treatment of this hamiltonian is performed with the use of the irreducible tensor operator technique and symmetry of the system. A good agreement of the experimentally observed magnetic susceptibility and the results of calculation is obtained. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:290 / 294
页数:5
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