Coinage metal-assisted synthesis of heterocycles

被引：1106

作者：

Patil, Nitin T. ^{[1
]}

Yamamoto, Yoshinori ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

来源：

CHEMICAL REVIEWS | 2008年 / 108卷 / 08期

关键词：

D O I：

10.1021/cr050041j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A review on the coinage metals as with Cu, Ag, and Au is given regarding its uses in the synthesis of heterocycles. In addition, a discussion with the mechanism of the C-C and C-X bond formation reactions will be provided so as to show the activation of substrates and possible reaction pathways. Then, a description on the use of coinage metals as a sole catalyst for the synthesis of heterocycles is also offered. However, only the reactions where a heterocyclic ring that is essentially generated will only be discussed. Specific topics to be discussed include: the cyclization of unsaturated C-C bonds with tethered nucleophiles; cycloaddition reactions; the cycloisomerization of enynes/diynes; the intramolecular friedel-crafts-type reactions; reactions of α-Diazocarbonyl compounds; aziridination of olefins; N/O-vinylation/arylation; and finally, the radical cyclization of haloalkenes and haloalkynes.

引用

页码：3395 / 3442

页数：48

共 470 条

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