Self-assembly:: A minimalist route to the fabrication of nanomaterials

被引:56
作者
Lazzari, M [1 ]
Rodríguez-Abreu, C
Rivas, J
López-Quintela, MA
机构
[1] Univ Santiago de Compostela, Inst Technol Invest, Magnetism & Nanotechnol Lab, E-15782 Santiago De Compostela, Spain
[2] Univ Santiago de Compostela, Dept Phys Chem, Fac Chem, E-15782 Santiago De Compostela, Spain
[3] Univ Santiago de Compostela, Dept Appl Phys, Fac Phys, E-15782 Santiago De Compostela, Spain
关键词
self-assembly; nanofabrication; block copolymers; colloids; nanoparticles; peptides; self-assembled monolayers; amphiphiles; templating; mesoporous structures;
D O I
10.1166/jnn.2006.172
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Self-assembly of molecular or nonmolecular components by non-covalent interactions offers an invaluable tool for the preparation of discrete nanostructures and extended 2D and 3D materials, which are often not accessible by any other fabrication process. In this article we summarize the most recent advances in the generation of nanomaterials such as self-assembled monolayers (SAMs) and structures formed from amphiphilic molecules, colloids, peptides, and polymers by nontemplated self-assembly either at the solid state or in solution. The current status of templated self-assembly and the use of self-assembled structures as template and for patterning other materials is also covered. A special emphasis is placed on strategies presenting either original and somehow exploratory approaches, eventually combining bottom-up and top-down methods, or that concern methods for the production of materials with potential application, e.g., in photonics, as sensors, for drug delivery and electric and magnetic devices. In all the sections, we outline self-organization and applications enabled with self-separated block copolymers.
引用
收藏
页码:892 / 905
页数:14
相关论文
共 185 条
[51]   Transfer of a chemical substrate pattern into an island-forming diblock copolymer film [J].
Heier, J ;
Genzer, J ;
Kramer, EJ ;
Bates, FS ;
Walheim, S ;
Krausch, G .
JOURNAL OF CHEMICAL PHYSICS, 1999, 111 (24) :11101-11110
[52]   Silica hollow spheres by templating of catanionic vesicles [J].
Hentze, HP ;
Raghavan, SR ;
McKelvey, CA ;
Kaler, EW .
LANGMUIR, 2003, 19 (04) :1069-1074
[53]   Shear-induced grain boundary motion for lamellar phases in the weakly nonlinear regime -: art. no. 041504 [J].
Huang, ZF ;
Viñals, J .
PHYSICAL REVIEW E, 2004, 69 (04) :9
[54]   Electrochemical desorption of self-assembled monolayers noninvasively releases patterned cells from geometrical confinements [J].
Jiang, XY ;
Ferrigno, R ;
Mrksich, M ;
Whitesides, GM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (09) :2366-2367
[55]   Self-assembly of phase-segregated liquid crystal structures [J].
Kato, T .
SCIENCE, 2002, 295 (5564) :2414-2418
[56]  
Kim HC, 2001, ADV MATER, V13, P795, DOI 10.1002/1521-4095(200106)13:11<795::AID-ADMA795>3.0.CO
[57]  
2-1
[58]  
Klok HA, 2001, ADV MATER, V13, P1217, DOI 10.1002/1521-4095(200108)13:16<1217::AID-ADMA1217>3.0.CO
[59]  
2-D
[60]   DNH DEOXYRIBONUCLEOHELICATES - SELF ASSEMBLY OF OLIGONUCLEOSIDIC DOUBLE-HELICAL METAL-COMPLEXES [J].
KOERT, U ;
HARDING, MM ;
LEHN, JM .
NATURE, 1990, 346 (6282) :339-342