Chemical nitrogen fixation by molybdenum and tungsten complexes

被引：163

作者：

Hidai, M ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem & Biotechnol, Grad Sch Engn, Tokyo, Japan

来源：

COORDINATION CHEMISTRY REVIEWS | 1999年 / 185-6卷

关键词：

dinitrogen; nitrogen fixation; heterocycles; ammonia;

D O I：

10.1016/S0010-8545(98)00250-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nitrogen heterocycles, such as pyrroles, phthalimidines and pyridines, are synthesized starting from the ligating dinitrogen in Mo and W complexes of the type [M(N-2)(2)(L)(4)] (M = Mo, W; L = phosphine). Further, ammonia is formed from N-2 and H-2 at 55 degrees C and 1 atm by using a novel Ru/W bimetallic system, where N-2 and H-2 are activated on the W and Ru center, respectively. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：99 / 108

页数：10

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