Chemoselective benzylic C-H Activations for the preparation of condensed N-heterocycles

被引：112

作者：

Ren, Hongjun ^{[1
]}

Knochel, Paul ^{[1
]}

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 21期

关键词：

C-H activation; domino reactions; nitrogen heterocycles; palladium;

D O I：

10.1002/anie.200600111

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Buttoning up: A chemoselective domino reaction including one or two successive C-H activations serves to convert a range of readily available N-arylpyrroles into complex polycondensed N-heterocycles. The reaction is catalyzed by Pd(OAc)2 (5 mol%), and p-Tol3P (10 mol%) is added as the ligand (see scheme; Tol = tolyl). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3462 / 3465

页数：4

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