A novel C-H insertion via deoxygenation of amides by a Sm/SmI2 mixed system

被引：49

作者：

Ogawa, A ^{[1
]}

Takami, N ^{[1
]}

Nanke, T ^{[1
]}

Ohya, S ^{[1
]}

Hirao, T ^{[1
]}

Sonoda, N ^{[1
]}

机构：

[1] KANSAI UNIV,FAC ENGN,DEPT APPL CHEM,SUITA,OSAKA 564,JAPAN

来源：

TETRAHEDRON | 1997年 / 53卷 / 38期

关键词：

D O I：

10.1016/S0040-4020(97)00805-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A samarium/samarium diiodide mixed system successfully effects novel aminocyclopropanation and C-H insertion via the deoxygenation of amides. Styrenes undergo aminocyclopropanation by the reaction with aromatic amides, samarium metal, and samarium diiodide. Furthermore, the reaction of aliphatic amides with Sm/SmI2 in the presence of alkylbenzenes like toluene causes benzylic C-11 insertion givining the corresponding phenylethylamine derivatives in good yields. (C) 1997 Elsevier Science Ltd.

引用

页码：12895 / 12902

页数：8

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