A phen-terpy conjugate whose chelate coordination axes are orthogonal to one another and its zinc complex

被引：10

作者：

Champin, B ^{[1
]}

Sartor, V ^{[1
]}

Sauvage, JP ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, UMR 7177, Lab Chim Organomineral, F-67070 Strasbourg, France

来源：

NEW JOURNAL OF CHEMISTRY | 2006年 / 30卷 / 01期

关键词：

D O I：

10.1039/b511762c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new highly rigid ditopic ligand has been prepared which consists of a terpy fragment connected through its 4' position to the 3 position of a phen nucleus via a 1,4-phenylene linker. The chemical structure of the presently reported two-chelate ligand is such that the coordination axes of the two chelates are orthogonal to one another. The reaction of this phen-terpy conjugate with Zn2+ affords in good yield a dimeric structure, as shown by ES-MS and H-1 NMR spectroscopies.

引用

页码：22 / 25

页数：4

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