A phen-terpy conjugate whose chelate coordination axes are orthogonal to one another and its zinc complex

被引：10

作者：

Champin, B ^{[1
]}

Sartor, V ^{[1
]}

Sauvage, JP ^{[1
]}

机构：

[1] Univ Strasbourg, CNRS, UMR 7177, Lab Chim Organomineral, F-67070 Strasbourg, France

来源：

NEW JOURNAL OF CHEMISTRY | 2006年 / 30卷 / 01期

关键词：

D O I：

10.1039/b511762c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new highly rigid ditopic ligand has been prepared which consists of a terpy fragment connected through its 4' position to the 3 position of a phen nucleus via a 1,4-phenylene linker. The chemical structure of the presently reported two-chelate ligand is such that the coordination axes of the two chelates are orthogonal to one another. The reaction of this phen-terpy conjugate with Zn2+ affords in good yield a dimeric structure, as shown by ES-MS and H-1 NMR spectroscopies.

引用

页码：22 / 25

页数：4

共 37 条

[11] Photoinduced two-step energy transfer in a Re/Ru dinuclear complex as mediated by an interposed 'reservoir' unit [J].

Encinas, S ;

Barthram, AM ;

Ward, MD ;

Barigelletti, F ;

Campagna, S .

CHEMICAL COMMUNICATIONS, 2001, (03) :277-278

[12] Coordination assemblies from a Pd(II)-cornered square complex [J].

Fujita, M ;

Tominaga, M ;

Hori, A ;

Therrien, B .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :369-378

[13] SELF-ASSEMBLY OF SILVER(I) HELICATES [J].

GARRETT, TM ;

KOERT, U ;

LEHN, JM ;

RIGAULT, A ;

MEYER, D ;

FISCHER, J .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (07) :557-558

[14] 3,6-bis(2′-pyridyl)pyridazine (L) and its deprotonated form (L-H+)- as ligands for {(acac)2Run+} or {(bpy)2Rum+}:: investigation of mixed valency in [{(acac)2Ru}2(μ-L-H+)]0 and [{(bpy)2Ru}2(μ-L-H+)]4+ by spectroelectrochemistry and EPR [J].

Ghumaan, S ;

Sarkar, B ;

Patra, S ;

Parimal, K ;

van Slageren, J ;

Fiedler, J ;

Kaim, W ;

Lahiri, GK .

DALTON TRANSACTIONS, 2005, (04) :706-712

[15] Dual emission from a family of conjugated dinuclear RuII complexes [J].

Glazer, EC ;

Magde, D ;

Tor, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (12) :4190-4192

[16] SYNTHESIS, STRUCTURE, AND PROPERTIES OF DINUCLEAR AND TRINUCLEAR RACK-TYPE RU-II COMPLEXES [J].

HANAN, GS ;

ARANA, CR ;

LEHN, JM ;

FENSKE, D .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (10) :1122-1124

[17]

Hori A, 2001, CHEM-EUR J, V7, P4142, DOI 10.1002/1521-3765(20011001)7:19<4142::AID-CHEM4142>3.0.CO

[18]

2-5

[19] A circular tris[2]catenane from molecular 'figure-of-eight' [J].

Hori, A ;

Yamashita, K ;

Kusukawa, T ;

Akasaka, A ;

Biradha, K ;

Fujita, M .

CHEMICAL COMMUNICATIONS, 2004, (16) :1798-1799

[20] Construction of triangular metallomacrocycles:: [M3(1,2-bis(2,2′: 6′,2"-terpyridin-4-yl-ethynyl)benzene)3] [M = Ru(II), Fe(II), 2Ru(II)Fe(II)] [J].

Hwang, SH ;

Moorefield, CN ;

Fronczek, FR ;

Lukoyanova, O ;

Echegoyen, L ;

Newkome, GR .

CHEMICAL COMMUNICATIONS, 2005, (06) :713-715

← 1 2 3 4 →