A periodic mesoporous organosilica containing electron acceptor viologen units

被引:91
作者
Alvaro, M
Ferrer, B
Fornés, V
García, H
机构
[1] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[2] Univ Politecn Valencia, Dept Quim, Valencia 46022, Spain
关键词
D O I
10.1039/b108964c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A periodic structured organosilica solid of the MCM-41 type containing 4,4'-bipyridinium presumably inserted on the walls that is stable after surfactant removal has been prepared; the ability of bipyridinium units to act as electron acceptor termini has been demonstrated by observation of the radical cation in the photochemical and thermal activation of the as-synthesized material.
引用
收藏
页码:2546 / 2547
页数:2
相关论文
共 13 条
[1]   Intrazeolite photochemistry .17. Zeolites as electron donors: Photolysis of methylviologen incorporated within zeolites [J].
Alvaro, M ;
Garcia, H ;
Garcia, S ;
Marquez, F ;
Scaiano, JC .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (16) :3043-3051
[2]   Periodic mesoporous organosilicas with organic groups inside the channel walls [J].
Asefa, T ;
MacLachlan, MJ ;
Coombs, N ;
Ozin, GA .
NATURE, 1999, 402 (6764) :867-871
[3]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843
[4]   INORGANIC SOLID ACIDS AND THEIR USE IN ACID-CATALYZED HYDROCARBON REACTIONS [J].
CORMA, A .
CHEMICAL REVIEWS, 1995, 95 (03) :559-614
[5]   PHOTOCHEMISTRY OF IODOCUPRATE(I) COMPLEXES [J].
HORVATH, O ;
FENDLER, JH ;
STEVENSON, KL .
INORGANIC CHEMISTRY, 1993, 32 (02) :227-230
[6]   Novel mesoporous materials with a uniform distribution of organic groups and inorganic oxide in their frameworks [J].
Inagaki, S ;
Guan, S ;
Fukushima, Y ;
Ohsuna, T ;
Terasaki, O .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) :9611-9614
[7]  
MacLachlan MJ, 2000, CHEM-EUR J, V6, P2507, DOI 10.1002/1521-3765(20000717)6:14<2507::AID-CHEM2507>3.0.CO
[8]  
2-9
[9]   Mesoporous sieves with unified hybrid inorganic/organic frameworks [J].
Melde, BJ ;
Holland, BT ;
Blanford, CF ;
Stein, A .
CHEMISTRY OF MATERIALS, 1999, 11 (11) :3302-3308
[10]  
MONK JA, 1998, VIOLOGENS PHYSICOCHE