Growing spatial correlations of particle displacements in a simulated liquid on cooling toward the glass transition

被引:165
作者
Donati, C [1 ]
Glotzer, SC
Poole, PH
机构
[1] Natl Inst Stand & Technol, Div Polymers, Gaithersburg, MD 20899 USA
[2] Natl Inst Stand & Technol, Ctr Theret & Computat Mat Sci, Gaithersburg, MD 20899 USA
[3] Univ Western Ontario, Dept Math Appl, London, ON N6A 5B7, Canada
关键词
D O I
10.1103/PhysRevLett.82.5064
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We define a correlation function that quantifies the spatial correlation of single-particle displacements in liquids and amorphous materials. We show that for an equilibrium liquid this function is related to fluctuations in a bulk dynamical variable. We evaluate this function using computer simulations of an equilibrium glass-forming liquid, and show that long range spatial correlations of displacements emerge and grow on cooling toward the mode coupling critical temperature.
引用
收藏
页码:5064 / 5067
页数:4
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