Polymer-Chain Encoding: Synthesis of Highly Complex Monomer Sequence Patterns by Using Automated Protocols

被引：57

作者：

Chan-Seng, Delphine ^{[1
]}

Zamfir, Mirela ^{[1
]}

Lutz, Jean-Francois ^{[1
]}

机构：

[1] CNRS, Inst Charles Sadron, UPR22, F-67034 Strasbourg 2, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 49期

基金：

欧洲研究理事会;

关键词：

automated synthesis; copolymerization; sequence-controlled polymers; single-chain arrays; synthesis design; SOLID-PHASE SYNTHESIS; POLYMERIZATIONS; COPOLYMERS; CHEMISTRY;

D O I：

10.1002/anie.201206371

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The automated sequence-controlled copolymerization of styrene and N-substituted maleimides allowed the production of unprecedented polymer microstructures (up to 65536 possible microstructural arrangements). Highly complex monomer sequence patterns were prepared using four N-substituted maleimides (see picture). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12254 / 12257

页数：4

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