A stable hydrido amido ruthenium complex bearing a tridentate iminophosphorane-phosphine-amine ligand

被引：41

作者：

Boubekeur, L ^{[1
]}

Ulmer, S ^{[1
]}

Ricard, L ^{[1
]}

Mézailles, N ^{[1
]}

Le Floch, P ^{[1
]}

机构：

[1] CNRS, UMR 7653, Dept Chim, Lab Heteroelements & Coordinat,Ecole Polytech, F-91128 Palaiseau, France

来源：

ORGANOMETALLICS | 2006年 / 25卷 / 02期

关键词：

D O I：

10.1021/om050738v

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A heterotridentate (P,N,N') ligand featuring phosphine, iminophosphorane, and amine groups has been prepared in high yield. The corresponding dichlororuthenium(II) complex reacts with base in 2-propanol to give a stable hydrido amido complex. The lack of hydrogens that are a to the amine allowed for the isolation and structural. characterization of this hydrido amido species by X-ray diffraction.

引用

收藏

页码：315 / 317

页数：3

相关论文

共 25 条

[11] Metal-promoted aromatic ring amination and deamination reactions at a diazo ligand coordinated to rhodium and ruthenium [J].

Das, C ;

Ghosh, AK ;

Hung, CH ;

Lee, GH ;

Peng, SM ;

Goswami, S .

INORGANIC CHEMISTRY, 2002, 41 (26) :7125-7135

[12] Ruthenium(II)-assisted asymmetric hydrogen transfer reduction of acetophenone using chiral tridentate phosphorus-containing ligands derived from (1R, 2R)-1,2-diaminocyclohexane [J].

Flores-López, CZ ;

Flores-López, LZ ;

Aguirre, G ;

Hellberg, LH ;

Parra-Hake, M ;

Somanathan, R .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 215 (1-2) :73-79

[13] THE PREPARATION AND STRUCTURE OF A DINUCLEAR ETA-2-H2 COMPLEX (P-N)(ETA-2-H2)RU(MU-CL)2(MU-H)RU(H)(PPH3)2, P-N = FE(ETA-C5H3(CHMENME2)P(I-PR)2-1,2)(ETA-C5H5) [J].

HAMPTON, C ;

CULLEN, WR ;

JAMES, BR ;

CHARLAND, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (20) :6918-6919

[14] SOLUTION STRUCTURE AND DYNAMICS OF 5-COORDINATE D6 COMPLEXES [J].

HOFFMAN, PR ;

CAULTON, KG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (15) :4221-4228

[15] FUNCTIONALIZATION OF BENZYLIC CARBON-HYDROGEN BONDS - MECHANISM AND SCOPE OF THE CATALYTIC SYNTHESIS OF INDOLES WITH [RU(DMPE)2] [J].

HSU, GC ;

KOSAR, WP ;

JONES, WD .

ORGANOMETALLICS, 1994, 13 (01) :385-396

[16] Dihydridoamine and hydridoamido complexes of ruthenium(II) with a tetradentate P-N-N-P donor ligand [J].

Li, TS ;

Churlaud, R ;

Lough, AJ ;

Abdur-Rashid, K ;

Morris, RH .

ORGANOMETALLICS, 2004, 23 (26) :6239-6247

[17]

Noyori R, 2001, ANGEW CHEM INT EDIT, V40, P40, DOI 10.1002/1521-3773(20010105)40:1<40::AID-ANIE40>3.0.CO

[18]

2-5

[19] Asymmetric transfer hydrogenation catalyzed by chiral ruthenium complexes [J].

Noyori, R ;

Hashiguchi, S .

ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (02) :97-102

[20]

PREGOSIN PS, 1979, BASIC PRINCIPLES PRO