Fused porphyrin-imidazole systems: new building blocks for synthesis of porphyrin arrays

被引：56

作者：

Crossley, MJ ^{[1
]}

McDonald, JA ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1999年 / 17期

关键词：

D O I：

10.1039/a905507j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of porphyrin-2,3-diones with aromatic aldehydes and NH4OAc in AcOH-CHCl3 affords 2-aryl-1H-imidazo[4,5-b]porphyrins which, with appropriate substitution, are useful building blocks for the synthesis of multi-porphyrin arrays; porphyrin-tetraones are similarly converted into the corresponding bis-fused systems.

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页码：2429 / 2431

页数：3

相关论文

共 12 条

[1] CONJUGATED PORPHYRIN LADDERS [J].

ANDERSON, HL .

INORGANIC CHEMISTRY, 1994, 33 (05) :972-981

[2] DIMERIC PORPHYRINS LINKED BY CONJUGATED GROUPS CONTAINING TRIPLE BONDS - THE CRYSTAL-STRUCTURE OF THE NICKEL OCTAETHYLPORPHYRIN DIMER BRIDGED BY 2,5-DIETHYNYLTHIOPHENE [J].

ARNOLD, DP ;

JAMES, DA ;

KENNARD, CHL ;

SMITH, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (18) :2131-2132

[3] SOME REACTIONS OF MESO-FORMYLOCTAETHYLPORPHYRIN [J].

ARNOLD, DP ;

JOHNSON, AW ;

MAHENDRAN, M .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1978, (04) :366-370

[4] PORPHYRIN DIMERS LINKED BY CONJUGATED BUTADIYNES [J].

ARNOLD, DP ;

NITSCHINSK, LJ .

TETRAHEDRON, 1992, 48 (40) :8781-8792

[5] Dimers and model monomers of nickel(II) octaethylporphyrin substituted by conjugated groups comprising combinations of triple bonds with double bonds and arenes .1. Synthesis and electronic spectra [J].

Arnold, DP ;

James, DA .

JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (11) :3460-3469

[6] RIGID, LATERALLY-BRIDGED BIS-PORPHYRIN SYSTEMS [J].

CROSSLEY, MJ ;

BURN, PL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (01) :39-40

[7] AN APPROACH TO PORPHYRIN-BASED MOLECULAR WIRES - SYNTHESIS OF A BIS(PORPHYRIN)TETRAONE AND ITS CONVERSION TO A LINEARLY CONJUGATED TETRAKISPORPHYRIN SYSTEM [J].

CROSSLEY, MJ ;

BURN, PL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (21) :1569-1571

[8] SYNTHESIS OF PORPHYRIN-2,3,12,13-TETRAONES AND PORPHYRIN-2,3,7,8-TETRAONES - BUILDING-BLOCKS FOR THE SYNTHESIS OF EXTENDED PORPHYRIN ARRAYS [J].

CROSSLEY, MJ ;

GOVENLOCK, LJ ;

PRASHAR, JK .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (23) :2379-2380

[9]

FORSTER T, 1959, DISCUSS FARADAY SOC, P7

[10]

Radziszewsky B., 1882, BER DTSCH CHEM GES, V15, P1493, DOI [DOI 10.1002/CBER.18820150207, 10.1002/cber.18820150207]