Synthesis of Uniform Polyaniline Nanofibers through Interfacial Polymerization

被引：158

作者：

Abdolahi, Ahmad ^{[1
]}

Hamzah, Esah ^{[1
]}

Ibrahim, Zaharah ^{[2
]}

Hashim, Shahrir ^{[3
]}

机构：

[1] Univ Teknol Malaysia, Fac Mech Engn, Johor Baharu 81310, Malaysia

[2] Univ Teknol Malaysia, Fac Biosci & Bioengn, Johor Baharu 81310, Malaysia

[3] Univ Teknol Malaysia, Fac Chem Engn, Johor Baharu 81310, Malaysia

来源：

MATERIALS | 2012年 / 5卷 / 08期

关键词：

polyaniline; nanofiber; interfacial polymerization; FESEM; XRD; FTIR;

D O I：

10.3390/ma5081487

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

The present paper aims to study the preparation of polyaniline nanofibers through simple interfacial polymerization. Ammonium persulfate, hydrochloric acid and chloroform were used as oxidant, dopant and organic solvent respectively. Field Emission Scanning Electron Microscopy (FESEM), X-ray diffraction and Fourier Transform Infrared Spectroscopy (FTIR) techniques were used to analyze the product. FESEM results show that polyaniline has nano-fiber morphology. XRD results show the crystalline properties of polyaniline nanofiber, and FTIR results confirmed the formation of polyaniline in different monomer/oxidant molar ratios. This study provides a better understanding on the synthesis of uniform polyaniline nanofibers through interfacial polymerization.

引用

页码：1487 / 1494

页数：8

共 25 条

[1]

Partial replacement of metallic zinc dust in heavy duty protective coatings by conducting polymer [J].

Armelin, Elaine ;

Marti, Mireia ;

Liesa, Francisco ;

Iribarren, Jose I. ;

Aleman, Carlos .

PROGRESS IN ORGANIC COATINGS, 2010, 69 (01) :26-30

[2]

Electrochemical synthesis of polyaniline and its comparison with chemically synthesized polyaniline [J].

Bhadra, Sambhu ;

Singha, Nikhil K. ;

Khastgir, Dipak .

JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 104 (03) :1900-1904

[3]

Synthesis of polyaniline nanofiber and anticorrosion property of polyaniline-epoxy composite coating for Q235 steel [J].

Ge, Cheng Yue ;

Yang, Xiao Gang ;

Hou, Bao Rong .

JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, 2012, 9 (01) :59-69

[4]

POLYANILINES WITH COVALENTLY BONDED ALKYL SULFONATES AS DOPING AGENT - SYNTHESIS AND PROPERTIES [J].

HANY, P ;

GENIES, EM ;

SANTIER, C .

SYNTHETIC METALS, 1989, 31 (03) :369-378

[5]

Nanostructured polyaniline sensors [J].

Huang, J ;

Virji, S ;

Weiller, BH ;

Kaner, RB .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (06) :1314-1319

[6]

A general chemical route to polyaniline nanofibers [J].

Huang, JX ;

Kaner, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (03) :851-855

[7]

Syntheses and applications of conducting polymer polyaniline nanofibers [J].

Huang, JX .

PURE AND APPLIED CHEMISTRY, 2006, 78 (01) :15-27

[8]

Polyaniline nanofibers prepared with ultrasonic irradiation [J].

Jing, XL ;

Wang, YY ;

Wu, D ;

She, L ;

Guo, Y .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (02) :1014-1019

[9]

Polyaniline: A polymer with many interesting intrinsic redox states [J].

Kang, ET ;

Neoh, KG ;

Tan, KL .

PROGRESS IN POLYMER SCIENCE, 1998, 23 (02) :277-324

[10]

Keiichi K, 1982, JPN J APPL PHYS, V21, P567

← 1 2 3 →