Coordination chemistry umpolung: A gallane ligand on a phosphine Lewis acceptor

被引:44
作者
Burford, N [1 ]
Ragogna, PJ
Robertson, KN
Cameron, TS
Hardman, NJ
Power, PP
机构
[1] Dalhousie Univ, Dept Chem, Halifax, NS B3H 4J3, Canada
[2] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA
关键词
D O I
10.1021/ja012081k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Pentaphenylphosphinophosphonium trifluoromethanesulfonate reacts with amino-iminogall(I)ane to effect quantitative substitution of Ph3P and formation of the first complex of a gallium Lewis base on a phosphine Lewis acid. Copyright © 2002 American Chemical Society.
引用
收藏
页码:382 / 383
页数:2
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