SYNTHESIS OF ONIO-SUBSTITUTED, DIONIO-SUBSTITUTED, AND TRIONIO-SUBSTITUTED PHOSPHINES - THE NUCLEOPHILIC BEHAVIOR OF DBN AND DBU TOWARD MAIN-GROUP ELECTROPHILES

被引：52

作者：

BOUHADIR, G ^{[1
]}

REED, RW ^{[1
]}

REAU, R ^{[1
]}

BERTRAND, G ^{[1
]}

机构：

[1] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE

来源：

HETEROATOM CHEMISTRY | 1995年 / 6卷 / 04期

关键词：

D O I：

10.1002/hc.520060415

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,5-Diazabicyclo[4.3.0]non-5-ene (DBN) and 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) react with chloro- and dichloro-phosphines leading to onio- and dionio-substituted phosphines. Similarly, onio-substituted silicon and tin derivatives are prepared; they are used as onio-substituent transfer reagents in the synthesis of a trionio-substituted phosphine.

引用

页码：371 / 375

页数：5

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