Surface functionalization of mesoporous and microporous activated carbons by immobilization of diamine

被引：56

作者：

Tamai, H ^{[1
]}

Shiraki, K ^{[1
]}

Shiono, T ^{[1
]}

Yasuda, H ^{[1
]}

机构：

[1] Hiroshima Univ, Dept Appl Chem, Grad Sch Engn, Higashihiroshima 7398527, Japan

来源：

JOURNAL OF COLLOID AND INTERFACE SCIENCE | 2006年 / 295卷 / 01期

关键词：

activated carbon; chemical treatment; diamine immobilization;

D O I：

10.1016/j.jcis.2005.08.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The introduction of amino groups on HNO3-treated microporous (AC(micro)-At) and mesoporous (AC(meso)-At) activated carbon, which was followed by thionyl chloride (SOCl2) treatment, by immobilization of diamine compounds was investigated in terms of change in pore characteristics. The immobilization was improved by treatment with SOCl2. The BET surface area of ACmicro-At largely decreased by immobilization of ethylenediamine (EDA) and hexamethylenediamine (HMDA). Decreases in BET surface area and pore volume of ACmeso-At by immobilization of EDA and HMDA were scarcely observed. These results suggest that amino groups introduced to mesoporous activated carbon are effective as functional groups for additional reactions. (c) 2005 Elsevier Inc. All rights reserved.

引用

页码：299 / 302

页数：4

共 19 条

[1] Amination of activated carbon and adsorption characteristics of its aminated surface [J].

Abe, M ;

Kawashima, K ;

Kozawa, K ;

Sakai, H ;

Kaneko, K .

LANGMUIR, 2000, 16 (11) :5059-5063

[2] Anchoring of organic molecules onto activated carbon [J].

Alves, JAC ;

Freire, C ;

de Castro, B ;

Figueiredo, JL .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2001, 189 (1-3) :75-84

[3] THE DETERMINATION OF PORE VOLUME AND AREA DISTRIBUTIONS IN POROUS SUBSTANCES .1. COMPUTATIONS FROM NITROGEN ISOTHERMS [J].

BARRETT, EP ;

JOYNER, LG ;

HALENDA, PP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (01) :373-380

[4] Influence of HNO3 oxidation on the structure and adsorptive properties of corncob-based activated carbon [J].

El-Hendawy, ANA .

CARBON, 2003, 41 (04) :713-722

[5] Novel activation process for preparing highly microporous and mesoporous activated carbons [J].

Hu, ZH ;

Srinivasan, MP ;

Ni, YM .

CARBON, 2001, 39 (06) :877-886

[6] AMINATION AND AMMOXIDATION OF ACTIVATED CARBONS [J].

JANSEN, RJJ ;

VANBEKKUM, H .

CARBON, 1994, 32 (08) :1507-1516

[7] Effects of activated carbon surface chemistry and pore structure on the adsorption of organic contaminants from aqueous solution [J].

Li, L ;

Quinlivan, PA ;

Knappe, DRU .

CARBON, 2002, 40 (12) :2085-2100

[8] Surface chemistry, pore sizes and adsorption properties of activated carbon fibers and precursors treated with ammonia [J].

Mangun, CL ;

Benak, KR ;

Economy, J ;

Foster, KL .

CARBON, 2001, 39 (12) :1809-1820

[9] Adsorption of dyes on activated carbons: influence of surface chemical groups [J].

Pereira, MFR ;

Soares, SF ;

Orfao, JJM ;

Figueiredo, JL .

CARBON, 2003, 41 (04) :811-821

[10] Chemical modification of carbon fiber surfaces by nitric acid oxidation followed by reaction with tetraethylenepentamine [J].

Pittman, CU ;

He, GR ;

Wu, B ;

Gardner, SD .

CARBON, 1997, 35 (03) :317-331

← 1 2 →