Oxidative Coupling Reactions of Grignard Reagents with Nitrous Oxide

被引：48

作者：

Kiefer, Gregor ^{[1
]}

Jeanbourquin, Loic ^{[1
]}

Severin, Kay ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 24期

基金：

瑞士国家科学基金会;

关键词：

copper; Grignard reagents; homogeneous catalysis; iron; nitrous oxide; ARYL; ACTIVATION; ALKENES; KETONIZATION; CHEMISTRY; ALCOHOLS; COMPLEX; OXYGEN; ETHER; TEMPO;

D O I：

10.1002/anie.201302471

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalysis with laughing gas: N2O in combination with transition-metal catalysts allow the oxidative homo- and cross-coupling of Grignard reagents. The reactions can be performed under mild conditions despite the inert character of N2O. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6302 / 6305

页数：4

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