Chemical modification of hydrogenated diamond surface using benzoyl peroxides

被引：58

作者：

Tsubota, T

Hirabayashi, O

Ida, S

Nagaoka, S

Nagata, M

Matsumoto, Y

机构：

[1] Kumamoto Ind Res Inst, Mat Dev Dept, Kumamoto 8620901, Japan

[2] Kumamoto Univ, Fac Engn, Dept Appl Chem & Biochem, Kumamoto 8608555, Japan

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2002年 / 4卷 / 05期

关键词：

D O I：

10.1039/b107349b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The chemical reaction of a hydrogenated diamond surface with the radical initiator benzoyl peroxide was performed in order to investigate the reactivity of the diamond surface. It was found that the hydrogen atoms on the diamond surface are abstracted by the radical species generated from benzoyl peroxide. The reaction rate was calculated from the experimental data. The hydrogen abstracted diamond surface reacts with radical species generated from the benzoyl peroxide, not with the solvent.

引用

页码：806 / 811

页数：6

共 15 条

[1] INTERACTION OF CHLORINE WITH HYDROGENATED DIAMOND SURFACE [J].

ANDO, T ;

YAMAMOTO, K ;

SUEHARA, S ;

KAMO, M ;

SATE, Y ;

SHIMOSAKI, S ;

NISHITANIGAMO, M .

JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 1995, 42 (02) :285-292

[2] Chemical modification of diamond surfaces using a chlorinated surface as an intermediate state [J].

Ando, T ;

NishitaniGamo, M ;

Rawles, RE ;

Yamamoto, K ;

Kamo, M ;

Sato, Y .

[3] THERMAL HYDROGENATION OF DIAMOND SURFACES STUDIED BY DIFFUSE REFLECTANCE FOURIER-TRANSFORM INFRARED, TEMPERATURE-PROGRAMMED DESORPTION AND LASER RAMAN-SPECTROSCOPY [J].

ANDO, T ;

ISHII, M ;

KAMO, M ;

SATO, Y .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (11) :1783-1789

[4] DIFFUSE-REFLECTANCE INFRARED FOURIER-TRANSFORM STUDY OF THE DIRECT THERMAL FLUORINATION OF DIAMOND POWDER SURFACES [J].

ANDO, T ;

YAMAMOTO, K ;

KAMO, M ;

SATO, Y ;

TAKAMATSU, Y ;

KAWASAKI, S ;

OKINO, F ;

TOUHARA, H .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1995, 91 (18) :3209-3212

[5] Direct interaction of elemental fluorine with diamond surfaces [J].

Ando, T ;

Yamamoto, K ;

Matsuzawa, M ;

Takamatsu, Y ;

Kawasaki, S ;

Okino, F ;

Touhara, H ;

Kamo, M ;

Sato, Y .

[6] Halogenation and butylation of diamond surfaces by reactions in organic solvents [J].

Ikeda, Y ;

Saito, T ;

Kusakabe, K ;

Morooka, S ;

Maeda, H ;

Taniguchi, Y ;

Fujiwara, Y .

[7]

IKEDA Y, 1997, P ELECTROCHEM SOC, P390

[8] Electrochemical modification of boron-doped chemical vapor deposited diamond surfaces with covalently bonded monolayers [J].

Kuo, TC ;

McCreery, RL ;

Swain, GM .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 1999, 2 (06) :288-290

[9] Photochemical modification of diamond surfaces [J].

Miller, JB ;

Brown, DW .

LANGMUIR, 1996, 12 (24) :5809-5817

[10]

NISHITANIGAMO M, 1997, P 4 NIRIM INT S ADV, P121

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