Ordering and Stabilization of Metal-Organic Coordination Chains by Hierarchical Assembly through Hydrogen Bonding at a Surface

被引：59

作者：

Langner, Alexander ^{[3
]}

Tait, Steven L. ^{[3
]}

Lin, Nian ^{[3
]}

Chandrasekar, Rajadurai ^{[2
]}

Ruben, Mario ^{[2
]}

Kern, Klaus ^{[1
,3
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Phys Nanostruct, CH-1015 Lausanne, Switzerland

[2] Inst Nanotechnol Forschungszentrum, Karlsruhe, Germany

[3] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 46期

关键词：

copper; scanning probe microscopy; self-assembly; supramolecular chemistry; surface chemistry;

D O I：

10.1002/anie.200803124

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Supramolecular glue: One-dimensional copper-pyridyl coordination chains on a Cu(100) surface are stabilized and ordered by dicarboxylic ligands through hydrogen-bonding interactions. This hierarchical bonding motif demonstrates a strategy for developing complex, yet well-ordered, supramolecular surface structures by self-assembly, such as these stable islands (see picture) with a one-dimensional coordination character. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8835 / 8838

页数：4

共 43 条

[1]

[Anonymous], ANGEW CHEM

[2] Molecular architectonic on metal surfaces [J].

Barth, Johannes V. .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 2007, 58 :375-407

[3] Engineering atomic and molecular nanostructures at surfaces [J].

Barth, JV ;

Costantini, G ;

Kern, K .

NATURE, 2005, 437 (7059) :671-679

[4] Stereochemical effects in supramolecular self-assembly at surfaces:: 1-D versus 2-D enantiomorphic ordering for PVBA and PEBA on Ag(111) [J].

Barth, JV ;

Weckesser, J ;

Trimarchi, G ;

Vladimirova, M ;

De Vita, A ;

Cai, CZ ;

Brune, H ;

Günter, P ;

Kern, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (27) :7991-8000

[5]

Biradha K, 2000, ANGEW CHEM INT EDIT, V39, P3843, DOI 10.1002/1521-3773(20001103)39:21<3843::AID-ANIE3843>3.0.CO

[6]

2-#

[7] Self-assembly of 1-nitronaphthalene on Au(111) [J].

Böhringer, M ;

Morgenstern, K ;

Schneider, WD ;

Wühn, M ;

Wöll, C ;

Berndt, R .

SURFACE SCIENCE, 2000, 444 (1-3) :199-210

[8] Supermolecules by design [J].

Caulder, DL ;

Raymond, KN .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) :975-982

[9] Two-dimensional supramolecular self-assembly probed by scanning tunneling microscopy [J].

De Feyter, S ;

De Schryver, FC .

CHEMICAL SOCIETY REVIEWS, 2003, 32 (03) :139-150

[10]

FUJITA M, 1995, TETRAHEDRON LETT, V36, P5247

← 1 2 3 4 5 →