Ordering and Stabilization of Metal-Organic Coordination Chains by Hierarchical Assembly through Hydrogen Bonding at a Surface

被引：59

作者：

Langner, Alexander ^{[3
]}

Tait, Steven L. ^{[3
]}

Lin, Nian ^{[3
]}

Chandrasekar, Rajadurai ^{[2
]}

Ruben, Mario ^{[2
]}

Kern, Klaus ^{[1
,3
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Phys Nanostruct, CH-1015 Lausanne, Switzerland

[2] Inst Nanotechnol Forschungszentrum, Karlsruhe, Germany

[3] Max Planck Inst Festkorperforsch, D-70569 Stuttgart, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 46期

关键词：

copper; scanning probe microscopy; self-assembly; supramolecular chemistry; surface chemistry;

D O I：

10.1002/anie.200803124

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Supramolecular glue: One-dimensional copper-pyridyl coordination chains on a Cu(100) surface are stabilized and ordered by dicarboxylic ligands through hydrogen-bonding interactions. This hierarchical bonding motif demonstrates a strategy for developing complex, yet well-ordered, supramolecular surface structures by self-assembly, such as these stable islands (see picture) with a one-dimensional coordination character. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8835 / 8838

页数：4

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