Ferroelectric phase transition in Ba5RTi3Nb7O30 [R = Nd, Eu, Gd] ceramics

被引:52
作者
Choudhary, RNP [1 ]
Shannigrahi, SR [1 ]
Singh, AK [1 ]
机构
[1] Indian Inst Technol, Dept Phys, Kharagpur 721302, W Bengal, India
关键词
polycrystalline; ferroelectric; tungsten-bronze structure; dielectric constant; electrical conduction;
D O I
10.1007/BF02745689
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Polycrystalline samples of Ba5RTi3Nb7O30 [R = Nd, Eu, Gd], were prepared using high-temperature solid-state reaction technique. Preliminary X-ray structural analysis of the compounds shows the formation of single phase compounds (orthorhombic crystal system) at room temperature. Detailed studies of dielectric properties (epsilon, tan delta, sigma) as a function of frequency (400 Hz to 10 kHz) and temperature (30 degrees to 380 degrees C) show that these compounds exhibit diffuse ferroelectric phase transition.
引用
收藏
页码:975 / 979
页数:5
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WUL BK, 1945, CR ACAD SCI URSS, V46, P133