Exfoliation of Crystalline 2D Carbon Nitride: Thin Sheets, Scrolls and Bundles via Mechanical and Chemical Routes

被引：70

作者：

Bojdys, Michael J. ^{[1
,2
]}

Severin, Nikolai ^{[3
]}

Rabe, Juergen P. ^{[3
]}

Cooper, Andrew I. ^{[1
,2
]}

Thomas, Arne ^{[4
]}

Antonietti, Markus ^{[5
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

[2] Univ Liverpool, Ctr Mat Discovery, Liverpool L69 7ZD, Merseyside, England

[3] Humboldt Univ, Inst Phys, D-12489 Berlin, Germany

[4] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

[5] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2013年 / 34卷 / 10期

基金：

英国工程与自然科学研究理事会;

关键词：

carbon nitride; exfoliation; graphite; layered material; POTASSIUM-GRAPHITE; ROOM-TEMPERATURE; SURFACE-AREA; POLYMERIZATION;

D O I：

10.1002/marc.201300086

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The carbon nitride poly(triazine imide) with intercalated bromide ions is a layered, graphitic material of 2D covalently bonded molecular sheets with an exceptionally large gallery height of 3.52 angstrom due to the intercalated bromide anions. The material can be cleaved both mechanically and chemically into thin sheets and scrolls analogous to the carbon-only systems graphite and graphene.

引用

页码：850 / 854

页数：5

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