A porous coordination framework for highly sensitive and selective solid-phase microextraction of non-polar volatile organic compounds

被引：181

作者：

He, Chun-Ting ^{[1
]}

Tian, Jing-Yu ^{[1
]}

Liu, Si-Yang ^{[1
]}

Ouyang, Gangfeng ^{[1
]}

Zhang, Jie-Peng ^{[1
]}

Chen, Xiao-Ming ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat & Technol, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China

来源：

CHEMICAL SCIENCE | 2013年 / 4卷 / 01期

关键词：

THIN-FILMS; CHROMATOGRAPHIC-SEPARATION; WATER SAMPLES; GEL TECHNIQUE; METAL; GROWTH; ETHYLBENZENE; OPTIMIZATION; ADSORPTION; CHEMISTRY;

D O I：

10.1039/c2sc21181e

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

A porous metal azolate framework [Zn(mpba)] (MAF-X8, H(2)mpba = 4-(3,5-dimethylpyrazol-4-yl)benzoic acid) with large, hydrophobic, one-dimensional channels and good thermal/chemical stability was synthesized and characterized. High-quality MAF-X8 thin films were grown on stainless-steel fibers for solid-phase microextraction (SPME), which showed high sensitivity and selectivity towards non-polar volatile organic compounds.

引用

收藏

页码：351 / 356

页数：6

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