Synthesis of a highly thermally stable octupolar polyimide for nonlinear optics

被引:42
作者
Le Bouder, T
Maury, O
Le Bozec, H
Ledoux, I
Zyss, J
机构
[1] Univ Rennes 1, Inst Chim, Lab Chim Coordinat & Catalyse, CNRS,UMR 6509, F-35042 Rennes, France
[2] ENS Cachan, Lab Phys Quant Mol, F-94235 Cachan, France
关键词
D O I
10.1039/b108099g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new polyimide with covalently incorporated 4,4'-bis-( dialkylaminostyryl)- 2,2'-bipyridine chromophores is described which allows the synthesis of the corresponding NLO octupolar metallo-polymer.
引用
收藏
页码:2430 / 2431
页数:2
相关论文
共 22 条
[1]   Synthesis and molecular hyperpolarisabilities of donor-acceptor bipyridyl metal complexes (M = Re, Zn, Hg) [J].
Bourgault, M ;
Baum, K ;
Le Bozec, H ;
Pucetti, G ;
Ledoux, I ;
Zyss, J .
NEW JOURNAL OF CHEMISTRY, 1998, 22 (05) :517-522
[2]   OPTICAL NONLINEARITIES IN CHEMISTRY - INTRODUCTION [J].
BURLAND, DM .
CHEMICAL REVIEWS, 1994, 94 (01) :1-2
[3]   Synthesis and characterisation of an octupolar polymer and new molecular octupoles with off-resonant third order optical nonlinearities [J].
Chérioux, F ;
Maillotte, H ;
Audebert, P ;
Zyss, J .
CHEMICAL COMMUNICATIONS, 1999, (20) :2083-2084
[4]   HYPER-RAYLEIGH SCATTERING IN SOLUTION [J].
CLAYS, K ;
PERSOONS, A .
PHYSICAL REVIEW LETTERS, 1991, 66 (23) :2980-2983
[5]   CHIRAL METAL-COMPLEXES WITH LARGE OCTUPOLAR OPTICAL NONLINEARITIES [J].
DHENAUT, C ;
LEDOUX, I ;
SAMUEL, IDW ;
ZYSS, J ;
BOURGAULT, M ;
LEBOZEC, H .
NATURE, 1995, 374 (6520) :339-342
[6]   New bipyridyl ligands bearing azo- and imino-linked chromophores. Synthesis and nonlinear optical studies of related dipolar zinc complexes [J].
Hilton, A ;
Renouard, T ;
Maury, O ;
Le Bozec, H ;
Ledoux, I ;
Zyss, J .
CHEMICAL COMMUNICATIONS, 1999, (24) :2521-2522
[7]   Second-order nonlinear optical active calix[4]arene polyimides suitable for frequency doubling in the UV region [J].
Kenis, PJA ;
Noordman, OFJ ;
vanHulst, NF ;
Engbersen, JFJ ;
Reinhoudt, DN ;
Hams, BHM ;
vanderVorst, CPJM .
CHEMISTRY OF MATERIALS, 1997, 9 (02) :596-601
[8]  
Le Bouder T, 1998, TETRAHEDRON LETT, V39, P6869
[9]  
Le Bozec H, 2000, EUR J INORG CHEM, P229
[10]  
LEBOUDER T, 2000, THESIS U RENNES