Pentanuclear octacyanotungstate(V)-based molecule with a high spin ground state S=13/2

被引：85

作者：

Podgajny, R

Desplanches, C

Sieklucka, B

Sessoli, R

Villar, V

Paulsen, C

Wernsdorfer, W

Dromzée, Y

Verdaguer, M

机构：

[1] Jagiellonian Univ, Fac Chem, PL-30060 Krakow, Poland

[2] Univ Paris 06, Unite Assoc CNRS 7071, Lab Chim Inorgan & Mat Mol, F-75252 Paris 05, France

[3] Univ Florence, Dept Chem, I-50144 Florence, Italy

[4] CNRS, Ctr Rech Tres Basses Temp, F-38054 Grenoble, France

[5] CNRS, Lab Louis Neel, F-38054 Grenoble, France

来源：

INORGANIC CHEMISTRY | 2002年 / 41卷 / 05期

关键词：

D O I：

10.1021/ic010679n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pentanuclear octacyanotungstate (V)-based molecules [Mn-II(bpy)(2)][Mn-II(bpy)(2)(H2O)](2)[W-V(CN)(8)](2).7H(2)O are V-shaped and packed into a broken chainlike structure (because of aromatic pi-pi stacking of the bpy rings) forming infinite linear columns. The compound exhibits intramolecular antiferromagnetic coupling between Mn-II and W-V ions, which leads to a high spin g-round state S = 13/2. Long-range intermolecular ferromagnetic ordering occurs at 0.66 K and prevents the observation of single molecule magnet behavior. [GRAPHICS] RAPHICS]

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页码：1323 / +

页数：6

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