Preparation of planar chiral amino phenols based on the [2.2]paracyclophane backbone

被引：14

作者：

Dahmen, S

Bräse, S

机构：

[1] Univ Bonn, Kekule Inst Organ Chem & Biochem, D-53121 Bonn, Germany

[2] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany

来源：

TETRAHEDRON-ASYMMETRY | 2001年 / 12卷 / 20期

关键词：

D O I：

10.1016/S0957-4166(01)00497-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of various planar and central chiral secondary and tertiary amino phenols based on the [2.2]paracyclophane backbone is described, Planar chiral tertiary amino phenols are prepared by reductive amination of 5-formyl-4-hydroxy[2,2]paracyclophane (FHPC) with secondary amines, The reduction of imine and ketimine precursors, as well as the 1,2-addition to these compounds is also described. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：2845 / 2850

页数：6

共 40 条

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