Use of an organometallic reagent in water: Sc(OTf)(3)-catalyzed allylation reactions of aldehydes in micellar systems

被引:71
作者
Kobayashi, S [1 ]
Wakabayashi, T [1 ]
Oyamada, H [1 ]
机构
[1] JAPAN SCI & TECHNOL CORP, JST, CREST, SHINJUKU KU, TOKYO 162, JAPAN
关键词
D O I
10.1246/cl.1997.831
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Sc(OTf)(3)-catalyzed allylation reactions of aldehydes with tetraallyltin proceeded smoothly in micellar systems to afford the corresponding homoallylic alcohols in high yields. The reactions were successfully carried out in the presence of a small amount of a surfactant in water without using any organic solvents.
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页码:831 / 832
页数:2
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