Diastereoselective reactions of optically active gamma-substituted vinyl phosphine oxides

被引：20

作者：

Clayden, J ^{[1
]}

Nelson, A ^{[1
]}

Warren, S ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

TETRAHEDRON LETTERS | 1997年 / 38卷 / 19期

关键词：

D O I：

10.1016/S0040-4039(97)00658-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dehydration of diphenylphosphinoyl diols (synthesised by asymmetric dihydroxylation of allylic phosphine oxides) gives gamma-hydroxy vinyl phosphine oxides. Some diastereoselective reactions of vinyl phosphine oxides with hydrogen, carbon and heteroatomic nucleophiles are discussed. (C) 1997 Elsevier Science Ltd.

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页码：3471 / 3474

页数：4

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