Manipulating the cavity of a porous material changes the photoreactivity of included guests

被引:32
作者
Dewal, Mahender B. [1 ]
Xu, Yuewen [1 ]
Yang, Jun [1 ]
Mohammed, Fiaz [1 ]
Smith, Mark D. [1 ]
Shimizu, Linda S. [1 ]
机构
[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
关键词
D O I
10.1039/b805895d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Changing an ether to a ketone within the framework of a bisurea macrocycle has little effect on the supramolecular assembly of this building block into porous crystals but introduces a triplet sensitizer into the framework that dramatically alters the photochemical reactions of included guests.
引用
收藏
页码:3909 / 3911
页数:3
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