From the reactivity of N-heterocyclic carbenes to new chemistry in ionic liquids

被引：95

作者：

Canal, JP ^{[1
]}

Ramnial, T ^{[1
]}

Dickie, DA ^{[1
]}

Clyburne, JAC ^{[1
]}

机构：

[1] Simon Fraser Univ, Dept Chem, Burnaby, BC V5A 1S6, Canada

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 17期

关键词：

D O I：

10.1039/b512462j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N-Heterocyclic carbenes have numerous applications in synthetic chemistry. We detail the reactivity and chemistry of these molecules including investigations into their reactions with small reagents, their use for the preparation of polarised azines and their potential application as NLO materials. The chemistry of imidazolium salts, which are related to NHCs by the addition of a proton, is also discussed. New chemistry for ionic liquids is also revealed.

引用

页码：1809 / 1818

页数：10

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