Bis(diethylamino)carbene and the mechanism of dimerisation for simple diaminocarbenes

被引：49

作者：

Alder, RW ^{[1
]}

Chaker, L ^{[1
]}

Paolini, FPV ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 19期

关键词：

D O I：

10.1039/b409112d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(diethylamino) carbene is kinetically stable to dimerization in THF at ambient temperature; dimer formed during carbene generation arises from reaction of the carbene with the precursor formamidinium ion; this is probably the commonest route to tetraaminoethene dimers, and in a related case the intermediate protonated tetraaminoethene can be observed by NMR.

引用

页码：2172 / 2173

页数：2

共 16 条

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