Cathodic electrosynthesis of ceramic deposits

被引：51

作者：

Zhitomirsky, I

GalOr, L

机构：

[1] Israel Institute of Metals, Technion-Israel Inst. of Technology, Haifa

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 1996年 / 16卷 / 08期

关键词：

D O I：

10.1016/0955-2219(96)00002-7

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Cathodic electrosynthesis of TiO2, ZrO2 and ZrTiO4 deposits on platinum substrates was performed via hydrolysis of TiCl4 and ZrOCl2 salts dissolved in a mixed methanol-water solvent in presence of hydrogen peroxide by an electrogenerated base. The deposits were characterized bq, XRD, TG/DTA, SEM ann EDS. Deposits as obtained were amorphous. The crystallization behaviour of the deposits has been studied Crystallite sizes were derived at different temperatures from X-ray broadening data. A possible mechanism of electrosynthesis ann the role of hydrogen peroxide are discussed.

引用

页码：819 / 824

页数：6

共 30 条

[1] SYNTHESIS OF SUPERCONDUCTIVE THIN-FILMS OF YBA2CU3O7-X BY A NONAQUEOUS ELECTRODEPOSITION PROCESS [J].