Combustion and gasification rates of lignocellulosic chars

被引:631
作者
Di Blasi, Colomba [1 ]
机构
[1] Univ Naples Federico II, Dipartimento Ingn Chim, I-80125 Naples, Italy
关键词
Lignocellulosic biomass; Pyrolysis; Char yield; Reactivity; Gasification; Combustion; Chemical kinetics; CONTINUOUS FLASH PYROLYSIS; CARBON-STEAM REACTION; GAS-PHASE PYROLYSIS; THERMAL-DECOMPOSITION; BIOMASS-PYROLYSIS; CO2; GASIFICATION; FLUIDIZED-BED; AIR GASIFICATION; WOOD PYROLYSIS; HEATING RATE;
D O I
10.1016/j.pecs.2008.08.001
中图分类号
O414.1 [热力学];
学科分类号
摘要
This review critically examines the state of the art of rate laws and kinetic constants for the gasification, with carbon dioxide and steam, and the combustion of chars produced from lignocellulosic fuels, including a brief outline about yields and composition of pyrolysis products. The analysis also gives space to the role played by various factors, such as heating rate, temperature and pressure of the pyrolysis stage, feedstock and content/composition of the inorganic matter, on char reactivity. Finally, directions for future research are suggested. (C) 2008 Published by Elsevier Ltd.
引用
收藏
页码:121 / 140
页数:20
相关论文
共 185 条
[31]   Devolatilization and heterogeneous combustion of wood fast pyrolysis oils [J].
Branca, C ;
Di Blasi, C ;
Elefante, R .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (04) :799-810
[32]   Devolatilization in the temperature range 300-600 K of liquids derived from wood pyrolysis and gasification [J].
Branca, C ;
Di Blasi, C ;
Russo, C .
FUEL, 2005, 84 (01) :37-45
[33]   Global kinetics of wood char devolatilization and combustion [J].
Branca, C ;
Di Blasi, C .
ENERGY & FUELS, 2003, 17 (06) :1609-1615
[34]   Global interinsic kinetics of wood oxidation [J].
Branca, C ;
Di Blasi, C .
FUEL, 2004, 83 (01) :81-87
[35]   GC/MS characterization of liquids generated from low-temperature pyrolysis of wood [J].
Branca, C ;
Giudicianni, P ;
Di Blasi, C .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (14) :3190-3202
[36]   Devolatilization and combustion kinetics of Quercus cerris bark [J].
Branca, Carmen ;
Iannace, Antonella ;
Di Blasi, Colomba .
ENERGY & FUELS, 2007, 21 (02) :1078-1084
[37]   Devolatilization of conventional pyrolysis oils generated from biomass and cellulose [J].
Branca, Carmen ;
Di Blasi, Colomba ;
Elefante, Rosario .
ENERGY & FUELS, 2006, 20 (05) :2253-2261
[38]   Multistep mechanism for the devolatilization of biomass fast pyrolysis oils [J].
Branca, Carmen ;
Di Blasi, Colomba .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2006, 45 (17) :5891-5899
[39]   THE TECHNICAL AND ECONOMIC-FEASIBILITY OF BIOMASS GASIFICATION FOR POWER-GENERATION [J].
BRIDGWATER, AV .
FUEL, 1995, 74 (05) :631-653
[40]   Principles and practice of biomass fast pyrolysis processes for liquids [J].
Bridgwater, AV .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1999, 51 (1-2) :3-22