A novel organic-inorganic hybrid with Anderson type polyanions as building blocks:: [(Gly)2Cu][Na(H2O)4Cr(OH)6Mo6O18]•9.5H2O (Gly = glycine)

被引：47

作者：

An, HY ^{[1
]}

Guo, YQ ^{[1
]}

Li, YG ^{[1
]}

Wang, EB ^{[1
]}

Lü, J ^{[1
]}

Xu, L ^{[1
]}

Hu, CW ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Poloxometalate Chem, Changchun 130024, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 04期

基金：

中国国家自然科学基金;

关键词：

oreanic-inorganic hybrid; anderson type polyanions; sodium ions; copper (II) coordination complexes;

D O I：

10.1016/j.inoche.2004.02.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new compound [(Gly)(2)Cu][Na(H2O)(4)Cr(OH)(6)Mo6O18].9.5H(2)O 1, has been synthesized and structurally characterized. Compound 1 exhibits an unusual two-dimensional (2D) window-like network constructed from [Cr(OH)(6)Mo6O18](3-) as building blocks, Na+ ions and Cu2+. coordination complexes as linkers, representing the first example of a 2D extended framework based on Anderson type polyanions. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：521 / 523

页数：3

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