Electron-Donating Tetrathienyl-Substituted Borole

被引：46

作者：

Araki, Takafumi ^{[1
]}

Fukazawa, Aiko ^{[1
]}

Yamaguchi, Shigehiro ^{[1
,2
]}

机构：

[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan

[2] CREST Japan Sci & Technol Agcy JST, Chikusa Ku, Nagoya, Aichi 4648602, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 22期

关键词：

antiaromaticity; borole; boron; conjugation; thiophene; SYSTEM; ANTIAROMATICITY; AROMATICITY; REDUCTION; PENTAARYLBOROLES; DIBENZOBOROLE; CONJUGATION; SHIFTS;

D O I：

10.1002/anie.201201156

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Green borole debuts: A heteroaryl-substituted borole with peripheral thienyl groups has a significantly high-lying HOMO in addition to a low-lying LUMO, and thus unusual photophysical and electrochemical properties. These results highlight the highly electron-donating character of the borole ring. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5484 / 5487

页数：4

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