Gold(I)-catalyzed stereoselective olefin cyclopropanation

被引：456

作者：

Johansson, MJ ^{[1
]}

Gorin, DJ ^{[1
]}

Staben, ST ^{[1
]}

Toste, FD ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 51期

关键词：

D O I：

10.1021/ja0552500

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A triphenylphosphinegold(I)-catalyzed cyclopropanation of olefins using propargyl esters as gold(I)-carbene precursors is reported. This reaction provided the basis for the use of a DTBM-SEGPHOS gold(I) complex as a catalyst in the enantioselective (up to 94% ee) preparation of vinyl cyclopropanes with high cis-selectivity. Copyright © 2005 American Chemical Society.

引用

页码：18002 / 18003

页数：2

共 35 条

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