Isolation and structural characterisation of a reactive chiral palladium(II) complex containing a ClO4 ligand

被引：46

作者：

Loh, SK

Mok, KF

Leung, PH

Andrew, JP

Williams, DJ

机构：

[1] NATL UNIV SINGAPORE, DEPT CHEM, SINGAPORE 117548, SINGAPORE

[2] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED, DEPT CHEM, LONDON SW7 2AY, ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 01期

关键词：

D O I：

10.1016/0957-4166(95)00417-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The organopalladium(II) complex [Pd(OClO3)(DMPP){(S)-CH3CH(1-C10H6)NMe(2)}] (where DMPP = 1-phenyl-3,4-dimethylphosphole) has been isolated. X-ray structural analysis of this reactive complex in the solid state revealed that the perchlorato ligand is bonded to Pd via one of its oxygen atoms and the DMPP is coordinated as a mondentate ligand via phosphorus. In noncoordinating solvents, conductivity measurements confirmed that the Pd-OClO3 bond is retained.

引用

页码：45 / 48

页数：4

共 16 条

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