Nitrogen-atom exchange mediated by nitrido complexes of molybdenum

被引：44

作者：

Gdula, RL ^{[1
]}

Johnson, MJA ^{[1
]}

Ockwig, NW ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 25期

关键词：

D O I：

10.1021/ic051859q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Nitrido complexes N Mo(OC(CF3)(2)Me)(3) (1) and N Mo(OC(CF3)(3))(3)(NCMe) (2) containing fluorinated alkoxide ancillary ligands are synthesized in 57% and 50% yield, respectively. Both complexes undergo N-atom exchange within hours at 30 degrees C with acetonitrile and benzonitrile in either THF-d(8) or CD2Cl2, as shown by N-15 NMR studies using labeled (NCMe)-N-15. In both solvents, 2 is the more active in this process. Additionally, both compounds are substantially more active in THF-d(8) than in CD2Cl2. Complex 2 crystallizes in the space group P2(1)/c, adopting a pseudo-square-pyramidal structure in which the nitrido moiety occupies the apical position, 1.633(3) angstrom away from Mo.

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页码：9140 / 9142

页数：3

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