A reinvestigation of beta-gallium oxide

被引:442
作者
Ahman, J
Svensson, G
Albertsson, J
机构
[1] Department of Inorganic Chemistry, Chalmers University of Technology
关键词
D O I
10.1107/S0108270195016404
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
beta-Ga2O3 contains two crystallographically different Ga atoms in the asymmetric unit, one with tetrahedral and the other with octahedral coordination geometry. The Ga-O distances are in the range 1.833(1)-1.863(2) Angstrom within the tetrahedra, but are longer within the octahedra [1.935 (2)-2.074 (1)Angstrom]. The O atoms have a distorted cubic close packing. The crystal structure of beta-gallium oxide has been determined previously by Geller [J. Chem. Phys. (1960), 33, 676-684].
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页码:1336 / 1338
页数:3
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