Alternating ring-opening metathesis copolymerization of bicyclo[2.2.1]hept-2-ene and cyclopentene

被引:26
作者
AlSamak, B [1 ]
Carvill, AG [1 ]
Hamilton, JG [1 ]
Rooney, JJ [1 ]
Thompson, JM [1 ]
机构
[1] QUEENS UNIV BELFAST,SCH CHEM,BELFAST BT9 5AG,ANTRIM,NORTH IRELAND
关键词
D O I
10.1039/a705046a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Almost alternating copolymers of bicyclo[2.2.1]hept-2-ene and cyclopentene have been formed by ring-opening metathesis polymerization using a RuCl3-phenol catalyst system; this highly novel result is attributed to differential steric influences exerted by a hydrogen-bonded solvent cage which encloses the catalyst site.
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页码:2057 / 2058
页数:2
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