Chemical vapor synthesis and luminescence properties of nanocrystalline cubic Y2O3:Eu

被引:180
作者
Konrad, A [1 ]
Fries, T
Gahn, A
Kummer, F
Herr, U
Tidecks, R
Samwer, K
机构
[1] Univ Augsburg, Inst Phys, D-86135 Augsburg, Germany
[2] Osram GmbH, D-86830 Schwabmunchen, Germany
[3] Osram GmbH, D-81536 Munich, Germany
关键词
D O I
10.1063/1.371177
中图分类号
O59 [应用物理学];
学科分类号
摘要
Nanocrystalline europium doped yttria was synthesized using a chemical vapor technique. The powder was characterized by x-ray diffraction, transmission electron microscopy, and ultraviolet spectroscopy. For the first time it was possible to obtain single phase Y2O3:Eu nanoparticles crystallized in the cubic structure with an average particle size of only 10 nm. The reflection, excitation, and emission spectra were studied. The nanoparticles show blue shifted absorption bands with respect to coarse grained material. (C) 1999 American Institute of Physics. [S0021-8979(99)01118-4].
引用
收藏
页码:3129 / 3133
页数:5
相关论文
共 32 条
[1]   DOPED NANOCRYSTALS OF SEMICONDUCTORS - A NEW CLASS OF LUMINESCENT MATERIALS [J].
BHARGAVA, RN ;
GALLAGHER, D ;
WELKER, T .
JOURNAL OF LUMINESCENCE, 1994, 60-1 :275-280
[2]   Doped nanocrystalline materials - Physics and applications [J].
Bhargava, RN .
JOURNAL OF LUMINESCENCE, 1996, 70 :85-94
[3]   Spectra and dynamics of monoclinic Eu2O3 and Eu3+:Y2O3 nanocrystals [J].
Bihari, B ;
Eilers, H ;
Tissue, BM .
JOURNAL OF LUMINESCENCE, 1997, 75 (01) :1-10
[4]  
Blasse G., 1994, LUMINESCENT MAT, DOI [10.1007/978-3-642-79017-1_1, DOI 10.1007/978-3-642-79017-1_1]
[6]  
Chang W., 1994, Nanostructured Materials, V4, P345, DOI 10.1016/0965-9773(94)90144-9
[7]   Nanostructured ceramics synthesized by chemical vapor condensation [J].
Chang, W ;
Skandan, G ;
Danforth, SC ;
Rose, M ;
Balogh, AG ;
Hahn, H ;
Kear, B .
NANOSTRUCTURED MATERIALS, 1995, 6 (1-4) :321-324
[8]   Laser spectroscopy of nanocrystalline Eu2O3 and Eu3+:Y2O3 [J].
Eilers, H ;
Tissue, BM .
CHEMICAL PHYSICS LETTERS, 1996, 251 (1-2) :74-78
[9]   THE EFFECT OF POWDER PREPARATION PROCESSES ON THE LUMINESCENT PROPERTIES OF YTTRIUM-OXIDE BASED PHOSPHOR MATERIALS [J].
ERDEI, S ;
ROY, R ;
HARSHE, G ;
JUWHARI, H ;
AGRAWAL, D ;
AINGER, FW ;
WHITE, WB .
MATERIALS RESEARCH BULLETIN, 1995, 30 (06) :745-753
[10]   EVIDENCE FOR EU+3-EMISSION FROM 2 SYMMETRY SITES IN Y2O3 - EU+3 [J].
FOREST, H ;
BAN, G .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1969, 116 (04) :474-&