Surface characterization of oxides grown on the Ti-13Nb-13Zr alloy and their corrosion protection

被引:77
作者
Duarte, Lais T. [1 ]
Biaggio, Sonia R. [1 ]
Rocha-Filho, Romeu C. [1 ]
Bocchi, Nerilso [1 ]
机构
[1] Univ Fed Sao Carlos, Dept Quim, BR-13560970 Sao Carlos, SP, Brazil
关键词
Alloy; EIS; SEM; Anodic films; Oxide coatings; Passive films; MICRO-ARC OXIDATION; TITANIUM-ALLOYS; ELECTROCHEMICAL-BEHAVIOR; TI-6AL-4V; LAYERS; TI; HYDROXYAPATITE; RESISTANCE; LASER; BIOMATERIALS;
D O I
10.1016/j.corsci.2013.02.007
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
Oxide films were formed on the biocompatible alloy Ti-13Nb-13Zr in a phosphate buffer at open-circuit potential (E-oc), potentiodynamically up to 8 V, or by micro-arc oxidation (MAO) at 300 V. Their electrochemical properties were assessed in a phosphate buffer saline solution (PBS). EIS and SEM results showed that the E-oc and potentiodynamically formed oxide films were compact and behave as a monolayer, while the MAO oxide was a bilayered film (compact inner and porous outer layers). Open-circuit potential and EIS resistance values indicated that the MAO oxide provides the best corrosion protection for the alloy in PBS. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:35 / 40
页数:6
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