Wear and corrosion behaviour of Ti-13Nb-13Zr and Ti-6Al-4V alloys in simulated physiological solution

被引:227
作者
Cvijovic-Alagic, I. [1 ]
Cvijovic, Z. [2 ]
Mitrovic, S. [3 ]
Panic, V. [4 ]
Rakin, M. [2 ]
机构
[1] Univ Belgrade, Inst Nucl Sci Vinca, Belgrade 11001, Serbia
[2] Univ Belgrade, Fac Technol & Met, Belgrade 11120, Serbia
[3] Univ Kragujevac, Fac Mech Engn, Kragujevac 34000, Serbia
[4] ICTM Ctr Electrochem, Belgrade 11000, Serbia
关键词
Ti orthopaedic alloys; Ringer's solution; Microstructures; Wear rate; Corrosion resistance; DRY SLIDING WEAR; TITANIUM-ALLOYS; ELECTROCHEMICAL CORROSION; FATIGUE BEHAVIOR; FRETTING WEAR; OXIDE-FILMS; BODY-FLUID; RESISTANCE; TI; ZR;
D O I
10.1016/j.corsci.2010.11.014
中图分类号
T [工业技术];
学科分类号
120111 [工业工程];
摘要
Wear and corrosion behaviour of cold-rolled Ti-13Nb-13Zr alloy, with martensitic microstructure, and Ti-6Al-4V ELI alloy, in martensitic and two-phase (alpha + beta) microstructural conditions, was studied in a Ringer's solution. The wear experiments were performed at room temperature with a normal load of 40 N and sliding speeds 0.26. 0.5 and 1.0 m/s. The corrosion behaviour was studied at 37 degrees C using open circuit potential-time measurements and potentiodynamic polarization. It was found that Ti-13Nb-13Zr alloy has a substantially lower wear resistance than Ti-6Al-4V ELI alloy in both microstructural conditions. Surface damage extent increases with sliding speed increase and is always smallest for martensitic Ti-6Al-4V ELI alloy with highest hardness. Both alloys exhibit spontaneous passivity in Ringer's solution. Corrosion potential values are similar for all three materials. However, Ti-13Nb-13Zr and martensitic Ti-6Al-4V ELI alloys show improved corrosion resistance comparatively to Ti-6Al-4V ELI alloy with (alpha + beta) microstructure. Martensitic Ti-6Al-4V ELI alloy possesses the best combination of both corrosion and wear resistance, although its corrosion resistance is found to be slightly higher than that of the Ti-13Nb-13Zr alloy. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:796 / 808
页数:13
相关论文
共 61 条
[1]
Phase transformations during cooling in α+β titanium alloys [J].
Ahmed, T ;
Rack, HJ .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1998, 243 (1-2) :206-211
[2]
Alam O, 2002, TRIBOL INT, V35, P357
[3]
Influence of plasma nitriding on fretting wear behaviour of Ti-6Al-4V [J].
Ali, M. Mubarak ;
Raman, S. Ganesh Sundara ;
Pathak, S. D. ;
Gnanamoorthy, R. .
TRIBOLOGY INTERNATIONAL, 2010, 43 (1-2) :152-160
[4]
In situ impedance spectroscopy study of the electrochemical corrosion of Ti and Ti-6Al-4V in simulated body fluid at 25 °C and 37 °C [J].
Alves, V. A. ;
Reis, R. Q. ;
Santos, I. C. B. ;
Souza, D. G. ;
Goncalves, T. de F. ;
Pereira-da-Silva, M. A. ;
Rossi, A. ;
da Silva, L. A. .
CORROSION SCIENCE, 2009, 51 (10) :2473-2482
[5]
[Anonymous], 2006, ELECTROCHIM ACTA, DOI [DOI 10.1016/j.electacta.2005.02.121, DOI 10.1016/J.ELECTACTA.2005.02.121]
[6]
CONTACT AND RUBBING OF FLAT SURFACES [J].
ARCHARD, JF .
JOURNAL OF APPLIED PHYSICS, 1953, 24 (08) :981-988
[7]
PREPARATION AND SURFACE SPECTROSCOPIC CHARACTERIZATION OF OXIDE-FILMS ON TI6A14V [J].
ASK, M ;
LAUSMAA, J ;
KASEMO, B .
APPLIED SURFACE SCIENCE, 1989, 35 (03) :283-301
[8]
The electrochemical behaviour of Ti-13Nb-13Zr alloy in various solutions [J].
Assis, S. L. ;
Wolynec, S. ;
Costa, I. .
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2008, 59 (09) :739-743
[9]
Electrochemical evaluation of Ti-13Nb-13Zr, Ti-6Al-4V and Ti-6Al-7Nb alloys for biomedical application by long-term immersion tests [J].
Assis, S. L. ;
Costa, I. .
MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION, 2007, 58 (05) :329-333
[10]
Corrosion Behavior of Ti-6Al-4V with Different Thermomechanical Treatments and Microstructures [J].
Atapour, M. ;
Pilchak, A. ;
Frankel, G. S. ;
Williams, J. C. ;
Fathi, M. H. ;
Shamanian, M. .
CORROSION, 2010, 66 (06)