Self-calibrated quantitative elemental analysis by laser-induced plasma spectroscopy: application to pigment analysis

被引：85

作者：

Borgia, Ilaria ^{[2
]}

Burgio, Lucia M. F. ^{[3
]}

Corsi, Michela ^{[1
]}

Fantoni, Roberta ^{[4
]}

Palleschi, Vincenzo ^{[1
]}

Salvetti, Azenio ^{[1
]}

Squarcialupi, Maria Cristina ^{[5
]}

Tognoni, Elisabetta ^{[1
]}

机构：

[1] CNR, Ist Fis Atom & Mol, Area Ric Pisa, I-56010 Pisa, Italy

[2] Univ Perugia, Dipartimento Chim, I-06100 Perugia, Italy

[3] UCL, Dept Chem, London, England

[4] ENEA, Dip Innovaz, Frascati, Italy

[5] Univ Florence, Dip Sci Terra, Florence, Italy

来源：

JOURNAL OF CULTURAL HERITAGE | 2000年 / 1卷

关键词：

atomic spectroscopy; quantitative analysis; laser spectroscopy; non-invasive techniques; in situ analysis;

D O I：

10.1016/S1296-2074(00)00174-6

中图分类号：

K85 [文物考古];

学科分类号：

0601 ;

摘要：

A new laser-based spectroscopic technique, called calibration-free LIPS (laser-induced plasma spectroscopy), is proposed for fast and precise elemental analysis in the field of cultural heritage conservation and study. Quantitative stratigraphic results, obtained by CF-LIPS on ancient Roman frescoe samples, are shown. The application of this calibration-free procedure frees the LIPS technique from the need of reference samples or an internal standard. This characteristic, along with the intrinsic speed (the whole process of data collection and analysis takes a few minutes) and precision (of the order of a few parts percent) make the CF-LIPS a viable technique for in situ quantitative analysis of artworks. (C) 2000 Editions scientifiques et medicales Elsevier SAS

引用

页码：S281 / S286

页数：6

共 23 条

[11] Transportable laser-induced breakdown spectroscopy (LIBS) instrument for field-based soil analysis
Cremers, DA
Ferris, MJ
Davies, M
[J]. ADVANCED TECHNOLOGIES FOR ENVIRONMENTAL MONITORING AND REMEDIATION, 1996, 2835 : 190 - 200
[12] Use of zirconium oxychloride to neutralize HF in the microwave-assisted acid dissolution of ceramic glazes for their chemical analysis by ICP-OES
Dondi, M
Fabbri, B
Mingazzini, C
[J]. TALANTA, 1998, 45 (06) : 1201 - 1210
[13] Time-resolved laser-induced breakdown spectroscopy: Application for qualitative and quantitative detection of fluorine, chlorine, sulfur, and carbon in air
Dudragne, L
Adam, P
Amouroux, J
[J]. APPLIED SPECTROSCOPY, 1998, 52 (10) : 1321 - 1327
[14] Matrix effects in the detection of Pb and Ba in soils using laser-induced breakdown spectroscopy
Eppler, AS
Cremers, DA
Hickmott, DD
Ferris, MJ
Koskelo, AC
[J]. APPLIED SPECTROSCOPY, 1996, 50 (09) : 1175 - 1181
[15] Goddard B. J., 1991, Transactions of the Institute of Measurement and Control, V13, P128, DOI 10.1177/014233129101300304
[16] DETERMINATION OF SULFUR-CONTENT IN STEEL BY LASER-PRODUCED PLASMA-ATOMIC EMISSION-SPECTROSCOPY
GONZALEZ, A
ORTIZ, M
CAMPOS, J
[J]. APPLIED SPECTROSCOPY, 1995, 49 (11) : 1632 - 1635
[17] DETECTION OF MERCURY IN AIR BY TIME-RESOLVED LASER-INDUCED BREAKDOWN SPECTROSCOPY TECHNIQUE
LAZZARI, C
DE ROSA, M
RASTELLI, S
CIUCCI, A
PALLESCHI, V
SALVETTI, A
[J]. LASER AND PARTICLE BEAMS, 1994, 12 (03) : 525 - 530
[18] LOGE GW, 1997, Patent No. 9715811
[19] On-line and in-situ detection of lead aerosols by plasma-spectroscopy and laser-excited atomic fluorescence spectroscopy
Neuhauser, RE
Panne, U
Niessner, R
Petrucci, GA
Cavalli, P
Omenetto, N
[J]. ANALYTICA CHIMICA ACTA, 1997, 346 (01) : 37 - 48
[20] Applications of laser-induced breakdown spectrometry
Song, K
Lee, YI
Sneddon, J
[J]. APPLIED SPECTROSCOPY REVIEWS, 1997, 32 (03) : 183 - 235

← 1 2 3 →