Facile synthesis of first generation ferrocene dendrimers by a convergent approach using ditopic conjugated dendrons

被引:37
作者
Palomero, J [1 ]
Mata, JA [1 ]
González, F [1 ]
Peris, E [1 ]
机构
[1] Univ Jaume 1, Dept Quim Inorgan & Organ, E-12080 Castellon de La Plana, Spain
关键词
D O I
10.1039/b108142j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile synthesis of new conjugated ferrocenyl-based dendrimers is reported and the compounds obtained have been fully characterized. The synthetic method consists of a two-step procedure, which combines olefination by the Wittig procedure and Pd-mediated C-C coupling, leading to high yields of first generation dendrimers with 3, 6 and 12 peripheral ferrocene units. The crystal structure of the conjugated ditopic ferrocenyl dendron and its aldehyde precursor are also described.
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收藏
页码:291 / 297
页数:7
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