Facile synthesis of first generation ferrocene dendrimers by a convergent approach using ditopic conjugated dendrons

被引：37

作者：

Palomero, J ^{[1
]}

Mata, JA ^{[1
]}

González, F ^{[1
]}

Peris, E ^{[1
]}

机构：

[1] Univ Jaume 1, Dept Quim Inorgan & Organ, E-12080 Castellon de La Plana, Spain

来源：

NEW JOURNAL OF CHEMISTRY | 2002年 / 26卷 / 03期

关键词：

D O I：

10.1039/b108142j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile synthesis of new conjugated ferrocenyl-based dendrimers is reported and the compounds obtained have been fully characterized. The synthetic method consists of a two-step procedure, which combines olefination by the Wittig procedure and Pd-mediated C-C coupling, leading to high yields of first generation dendrimers with 3, 6 and 12 peripheral ferrocene units. The crystal structure of the conjugated ditopic ferrocenyl dendron and its aldehyde precursor are also described.

引用

页码：291 / 297

页数：7

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