A Pd complex of a tridentate pincer CNC bis-carbene ligand as a robust homogenous Heck catalyst

被引:469
作者
Peris, E [1 ]
Loch, JA
Mata, J
Crabtree, RH
机构
[1] Univ Jaume 1, Dept Quim Inorgan & Organ, Castellon de La Plana 12080, Spain
[2] Yale Univ, Dept Chem, New Haven, CT 06520 USA
关键词
D O I
10.1039/b008038l
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The bis-carbene precursor, 1, gives a thermally very robust Pd(II) catalyst for Heck coupling that maintains activity even in boiling diethylacetamide (bp 184 degreesC) in air.
引用
收藏
页码:201 / 202
页数:2
相关论文
共 45 条
  • [1] Anionic Pd(0) and Pd(II) intermediates in palladium-catalyzed Heck and cross-coupling reactions
    Amatore, C
    Jutand, A
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2000, 33 (05) : 314 - 321
  • [2] DIBENZO[A,E]CYCLOOCTATETRAENE IN A PROPOSED TEST FOR HETEROGENEITY IN CATALYSTS FORMED FROM SOLUBLE PLATINUM GROUP METAL-COMPLEXES
    ANTON, DR
    CRABTREE, RH
    [J]. ORGANOMETALLICS, 1983, 2 (07) : 855 - 859
  • [3] A STABLE CRYSTALLINE CARBENE
    ARDUENGO, AJ
    HARLOW, RL
    KLINE, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (01) : 361 - 363
  • [4] Acetylene-bridged P,C,P′-ligands and corresponding cyclopalladated compounds
    Beletskaya, IP
    Chuchurjukin, AV
    Dijkstra, HP
    van Klink, GPM
    van Koten, G
    [J]. TETRAHEDRON LETTERS, 2000, 41 (07) : 1075 - 1079
  • [5] Tridentate SCS palladium(II) complexes: New, highly stable, recyclable catalysts for the heck reaction
    Bergbreiter, DE
    Osburn, PL
    Liu, YS
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (41) : 9531 - 9538
  • [6] Bielawski CW, 2000, ANGEW CHEM INT EDIT, V39, P2903, DOI 10.1002/1521-3773(20000818)39:16<2903::AID-ANIE2903>3.0.CO
  • [7] 2-Q
  • [8] N-heterocyclic carbenes Part 26.: N-heterocyclic carbene complexes of palladium(0):: synthesis and application in the Suzuki cross-coupling reaction
    Böhm, VPW
    Gstöttmayr, CWK
    Weskamp, T
    Herrmann, WA
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 595 (02) : 186 - 190
  • [9] *BRUK AN XRAY SYST, SAINT VERS 5 0
  • [10] SELECTIVE CATALYTIC DEHYDROGENATION OF ALKANES TO ALKENES
    BURK, MJ
    CRABTREE, RH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (26) : 8025 - 8032