Direct observation of orthogonal orientation of an aromatic ring attached to the carbene carbon in Fischer carbene complexes in solution: Diastereotopicity of benzyl protons as a stereochemical probe

被引：11

作者：

Amin, SR ^{[1
]}

Jayaprakash, KN ^{[1
]}

Nandi, M ^{[1
]}

Sathe, KM ^{[1
]}

Sarkar, A ^{[1
]}

机构：

[1] DIV ORGAN CHEM SYNTH,NATL CHEM LAB,PUNE 411008,MAHARASHTRA,INDIA

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 16期

关键词：

D O I：

10.1021/om960301a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diastereotopicity of methylene protons of benzyloxy and benzylamino groups in Fischer carbene complexes serves as a stereochemical probe to reveal orthogonal orientation of the aromatic rings attached to the carbene carbon with respect to the metal-carbene pi-plane in solution.

引用

页码：3528 / 3533

页数：6

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