Ceric(IV)-mediated reaction of methylenecyclopropanes in organic synthesis: A facile access to dihydrofurans and cyclobutanones

被引：31

作者：

Chen, WL

Huang, M

Zhou, HW

Ren, LJ

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310028, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

SYNTHESIS-STUTTGART | 2006年 / 04期

关键词：

methylenecyclopropanes; ammonium cerium(IV) nitrate; 1,3-dicarbonyl compounds; dihydrofuran; cyclobutanone;

D O I：

10.1055/s-2006-926298

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkylidenecyclopropanes undergo CAN-mediated addition reactions with 1,3-dicarbonyl compounds or ring rearrangement reactions leading to dihydrofuran and cyclobutanone derivatives, respectively, in moderate yields.

引用

页码：609 / 614

页数：6

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